Sweetness
Relative Sweetness*

Fructose     170
Invert sugar HFCS (42% F)     120
Sucrose     100
Xylitol     100
Glucose     75
High D. E. CS     60
Sorbitol     55
Mannitol     50
Regular CS     40
Galactose     30
Lactose     15


* Determined relative to 10% sucrose at room temperature. Relationship will change at different concentrations and at different temperatures.

Intermolecular H bond between sweet compound and recptor site.

AH/B System

AH proton to B - orbital distance is approximately 3 Å.



Kire hydrophobic site 3.5 Å from atom A of AH and 5.5 Å from B

Solubility of Sucrose and Dextrose


Polyols

Manufactured by hydrogenation of sugars

Propylene            Glycol Glycerol


Sorbitol                  Mannitol                   Xylitol


Functions of polyols in Foods

Viscosity
Sugar crystallization modification
Water binder
Solvent for colors, antioxidants, flavors
Dietetic Sweetener
"Cool" flavor"


Properties of Polyols

Property P. Glycol Glycerol Sorbitol Mannitol
         
W Wt. 76 92 1 82 1 82
         
Hydroscopicity High     Low
         
Sol.in water _   0.71 0.22
         
Viscosity Low     High
         
Oil solvent Good     Poor
         
Taste Bitter Sl Sweet Sweet Sweet

 

 

 

 

 

 

 

 

 

 

 

 

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